I agree with ICE. Outside of asking for what went on in the committee's heads, I'm willing to bet the justification was something like "lots of students could be in the hallway at once. We need to make sure we provide enough width to accommodate so many people going in different directions with classroom doors open... What number sounds good?" Someone else promptly yelled "6 feet". And that was that.
Breaking it down logically, having a hallway that wide makes sense. Classroom doors often (by code? I don't work on education projects) swing into the hallway and sometimes the classrooms are right across from each other. If both doors open at the same time, they could hit each other with a smaller hallway, which could be a bigger issue given how many students could be in the hallway at any one time. Even when that isn't the case, a door opening out into a, say, 44" hallway would block most of the traffic for a few seconds. Having extra space when there could be hundreds of people in the hallway allows for easier movement, especially when doors may be opening and closing often.
No idea if that's the justification they used, but that's what I would personally use. Again, I don't work on education projects, so I could be missing something.